1/6/2024 0 Comments Sulfuryl monal inhalantHydrolysis is faster under strongly acidic or basic conditions, with a broad pH-independent region between pH 4 and pH 12. An addition–elimination (A N + D N) mechanism would form a pentacoordinate sulfurane intermediate.Įxperimental evidence indicates that the reactions of aryl sulfate monoesters are mechanistically similar to those of phosphate monoesters. If a monoester follows a fully dissociative (D N + A N) mechanism, a sulfur trioxide intermediate would form, analogous to metaphosphate in the phosphoryl system. Sulfuryl transfer has available the same mechanistic pathways previously discussed for phosphoryl transfer ( Figure 2). Hengge, in Comprehensive Natural Products II, 2010 8.09.2.2 Sulfate Monoester Anions
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